As I said in last week's blog, I am working on a series of animation projects for six variations that flexible MOFs can take. For this week, I tackled the first three variations, which are Rigid Linker Twisting 0D, Spin-Crossover, and Rigid Linker 1D. The difference between Rigid Linker Twisting 0D and 1D is the ligands's rigidity, which connects the metals together. 0D means that all the ligands in a MOF are flexible. On the other hand, 1D means that one set of ligands are not flexible, but the other ligands can still bend. Again the flexible MOFs only change shape when a guest is exposed to it, such as gas. Lastly, Spin-Crossover is when the MOF shrinks when a guest is exposed. In addition, it will expand back to its original state when the guest is removed.
Here's a visual representation of the difference between Rigid Linker 0D and Rigid Linker 1D:
Note that the red metal spheres represent the a given metal and the bars that connect them are the ligands. The black bar means that the ligand is flexible and the blue bar means that the ligand is rigid.
Rigid Linker 0D
Rigid Linker 1D
I'm currently finishing up the final touches for the animations of the first three variations and hopefully I can upload them in the future. Essentially, it will show that as gas molecules enter a hypothetical MOF, it will bend, shrink, and compress if it's a Rigid Linker Twisting 0D, Spin-Crossover, or Rigid Linker 1D respectively. For next week, I will continue with the next couple of variations and explain how those change their structure. In addition, I will start diving into the specific details of how MOFs are created and what instruments are used.